Phase dependent structural perturbation of a robust multicomponent assembled icosahedral array.
Chem Commun (Camb)
; 54(77): 10824-10827, 2018 Sep 25.
Article
em En
| MEDLINE
| ID: mdl-30140821
ABSTRACT
We report on the assembly of three-fold axially compressed icosahedral arrays of the bowl shaped p-sulfonatocalix[4]arene molecules in the solid-state, intricately bound to dipicolinate and yttrium(iii) ions, with the compression reflected in Hirshfeld surface analyses. Solution studies show dissolution of the icosahedra intact, but with a geometrical rearrangement to regular icosahedra.
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MEDLINE
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En
Ano de publicação:
2018
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Article