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[Ln16] complexes (Ln = GdIII, DyIII): molecular analogues of natural minerals such as hydrotalcite.
Richardson, Paul; Hsu, Ting-Jung; Kuo, Che-Jung; Holmberg, Rebecca J; Gabidullin, Bulat; Rouzières, Mathieu; Clérac, Rodolphe; Murugesu, Muralee; Lin, Po-Heng.
Afiliação
  • Richardson P; Department of Chemistry and Biomolecular Sciences, University of Ottawa, ON K1N 6N5, Canada. m.murugesu@uottawa.ca.
  • Hsu TJ; Department of Chemistry, National Chung Hsing University, 250 Kuo Kang Rd., Taichung 402, Taiwan, R.O.C. poheng@dragon.nchu.edu.tw.
  • Kuo CJ; Department of Chemistry, National Chung Hsing University, 250 Kuo Kang Rd., Taichung 402, Taiwan, R.O.C. poheng@dragon.nchu.edu.tw.
  • Holmberg RJ; Department of Chemistry and Biomolecular Sciences, University of Ottawa, ON K1N 6N5, Canada. m.murugesu@uottawa.ca.
  • Gabidullin B; Department of Chemistry and Biomolecular Sciences, University of Ottawa, ON K1N 6N5, Canada. m.murugesu@uottawa.ca.
  • Rouzières M; CNRS, CRPP, UMR 5031, Pessac 33600, France and Univ. Bordeaux, CRPP, UMR 5031, Pessac 33600, France.
  • Clérac R; CNRS, CRPP, UMR 5031, Pessac 33600, France and Univ. Bordeaux, CRPP, UMR 5031, Pessac 33600, France.
  • Murugesu M; Department of Chemistry and Biomolecular Sciences, University of Ottawa, ON K1N 6N5, Canada. m.murugesu@uottawa.ca.
  • Lin PH; Department of Chemistry, National Chung Hsing University, 250 Kuo Kang Rd., Taichung 402, Taiwan, R.O.C. poheng@dragon.nchu.edu.tw.
Dalton Trans ; 47(37): 12847-12851, 2018 Oct 07.
Article em En | MEDLINE | ID: mdl-30141810
Two new hexadecanuclear lanthanide complexes employing the 1,5-bis(salicylidene)carbohydrazide (H2bsc) ligand are reported herein. These polynuclear aggregates crystallize in the R3[combining macron] space group, which is unprecedented in a family of lanthanide complexes with such high nuclearity. Magnetic susceptibility measurements reveal weak intramolecular interactions between the magnetic centres, and in the case of compound 2 (DyIII), single-molecule magnet properties are observed.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2018 Tipo de documento: Article
Texto completo
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2018 Tipo de documento: Article