FeCl3 as an Ion-Pairing Lewis Acid Catalyst. Formation of Highly Lewis Acidic FeCl2+ and Thermodynamically Stable FeCl4- To Catalyze the Aza-Diels-Alder Reaction with High Turnover Frequency.

Tomifuji, Rei; Maeda, Kazuki; Takahashi, Toshifumi; Kurahashi, Takuya; Matsubara, Seijiro

FeCl₃ as an Ion-Pairing Lewis Acid Catalyst. Formation of Highly Lewis Acidic FeCl₂⁺ and Thermodynamically Stable FeCl₄^- To Catalyze the Aza-Diels-Alder Reaction with High Turnover Frequency.

Tomifuji, Rei; Maeda, Kazuki; Takahashi, Toshifumi; Kurahashi, Takuya; Matsubara, Seijiro.

Afiliação

Tomifuji R; Department of Material Chemistry, Graduate School of Engineering , Kyoto University , Kyoto 615-8510 , Japan.
Maeda K; Department of Material Chemistry, Graduate School of Engineering , Kyoto University , Kyoto 615-8510 , Japan.
Takahashi T; Department of Material Chemistry, Graduate School of Engineering , Kyoto University , Kyoto 615-8510 , Japan.
Kurahashi T; Department of Material Chemistry, Graduate School of Engineering , Kyoto University , Kyoto 615-8510 , Japan.
Matsubara S; Department of Material Chemistry, Graduate School of Engineering , Kyoto University , Kyoto 615-8510 , Japan.

Org Lett ; 20(23): 7474-7477, 2018 12 07.

Article em En | MEDLINE | ID: mdl-30427692

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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2018 Tipo de documento: Article

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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2018 Tipo de documento: Article