Nickel-Catalyzed Cross-Coupling of Umpolung Carbonyls and Alkyl Halides.
J Org Chem
; 84(10): 6312-6322, 2019 May 17.
Article
em En
| MEDLINE
| ID: mdl-31002507
ABSTRACT
An effective nickel-catalyzed cross-coupling of Umpolung carbonyls and alkyl halides was developed. Complementary to classical alkylation techniques, this reaction utilizes Umpolung carbonyls as the environmentally benign alkyl nucleophiles, providing an efficient and selective catalytic alternative to the traditional use of highly reactive alkyl organometallic reagents.
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Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2019
Tipo de documento:
Article