Synthesis of ordered lamellar supermicroporous silica with rigid neutral and long-chain cationic composite templating route.

ABSTRACT

Using a mixture of neutral primary amine dehydroabietylamine (DHAA) and long-chain cetyltrimethyl ammonium bromide (CTAB) as the template, ordered lamellar supermicroporous silicas were synthesized with NaOH as the base source and tetraethylorthosilicate (TEOS) as the silica source. The concentrations of DHAA, CTAB, and NaOH in the synthesis system had great effects on the structural properties of the samples. When the molar ratio of components was nTEOSnCTABnDHAAnNaOHnH2O = 10.1140.004570.560, the material showed a lamellar phase with the highest ordering degree. By adding only a trace amount of DHAA into the synthesis system, the structure of the samples could be transformed from cubic phase to lamellar phase, since the added DHAA solubilized in CTAB micelles to change the effective surfactant ion pair packing parameter. The dosage of CTAB should be moderate; too high or too low will decay the ordering degree of the lamellar structure.A much higher concentration of NaOH resulted in an ethanol-rich solvent in which the DHAA did not solubilize in the micelles of CTAB, but adsorbed at the hydrophilic headgroup-solvent interface. Accordingly, a structural transformation from lamellar phase to hexagonal phase occurred.