Switching the enantioselectivity of nanoporous host materials by light.
Chem Commun (Camb)
; 55(60): 8776-8779, 2019 Jul 23.
Article
em En
| MEDLINE
| ID: mdl-31099346
ABSTRACT
A chiral photoswitchable nanoporous material with remote-controllable enantioselective adsorption capacity is presented. This metal-organic framework possesses both homochiral d-camphoric acid and light-responsive azobenzene moieties. Although the structure at the chiral moieties is unaffected, the trans-cis-azobenzene-photoisomerization changes the pore environment and, thus, switches the enantioselective adsorption behavior of the homochiral MOF.
Texto completo:
1
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2019
Tipo de documento:
Article