The MMCT excited state of a localized mixed valence cyanido-bridged RuII-Ru-RuII complex.
Dalton Trans
; 48(25): 9303-9309, 2019 Jun 25.
Article
em En
| MEDLINE
| ID: mdl-31166345
ABSTRACT
To investigate MMCT excited states of MV complexes, two symmetrical tetranuclear cyanido-bridged localized MV complexes RuIICNRuIII,III2NCRuII have been designed and synthesized. The ultrafast time-resolved transient absorption (TA) spectroscopy experiment reveals that the MMCT rate of 1 and 2 is 0.18 × 1014 s-1 (τ = 5.7 × 10-14 s) and 0.29 × 1013 s-1 (τ = 3.46 × 10-13 s), respectively, which suggests that the MMCT rate or the lifetime of the MMCT excited state may be controlled by a slight change of the substituent group on the metal center.
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MEDLINE
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2019
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Article