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Highly active bidentate N-heterocyclic carbene/ruthenium complexes performing dehydrogenative coupling of alcohols and hydroxides in open air.
Wang, Zhi-Qin; Tang, Xiao-Sheng; Yang, Zhao-Qi; Yu, Bao-Yi; Wang, Hua-Jing; Sang, Wei; Yuan, Ye; Chen, Cheng; Verpoort, Francis.
Afiliação
  • Wang ZQ; State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, 122 Luoshi Road, Wuhan 430070, P. R. China. chengchen@whut.edu.cn francis.verpoort@ghent.ac.kr and School of Materials Science and Engineering, Wuhan University of Technology, 122 Luos
  • Tang XS; Key Laboratory of Optoelectronic Technology and Systems (Ministry of Education) College of Optoelectronic Engineering, Chongqing University, Chongqing 400044, P. R. China.
  • Yang ZQ; School of Pharmaceutical Sciences, Jiangnan University, Wuxi 214122, China.
  • Yu BY; Key Laboratory of Urban Agriculture (North China), Ministry of Agriculture, Beijing University of Agriculture, Beinong Road 7, Beijing 102206, P. R. China.
  • Wang HJ; State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, 122 Luoshi Road, Wuhan 430070, P. R. China. chengchen@whut.edu.cn francis.verpoort@ghent.ac.kr.
  • Sang W; State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, 122 Luoshi Road, Wuhan 430070, P. R. China. chengchen@whut.edu.cn francis.verpoort@ghent.ac.kr and School of Materials Science and Engineering, Wuhan University of Technology, 122 Luos
  • Yuan Y; State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, 122 Luoshi Road, Wuhan 430070, P. R. China. chengchen@whut.edu.cn francis.verpoort@ghent.ac.kr.
  • Chen C; State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, 122 Luoshi Road, Wuhan 430070, P. R. China. chengchen@whut.edu.cn francis.verpoort@ghent.ac.kr.
  • Verpoort F; State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, 122 Luoshi Road, Wuhan 430070, P. R. China. chengchen@whut.edu.cn francis.verpoort@ghent.ac.kr and National Research Tomsk Polytechnic University, Lenin Avenue 30, Tomsk 634050, Russia
Chem Commun (Camb) ; 55(59): 8591-8594, 2019 Jul 18.
Article em En | MEDLINE | ID: mdl-31276134
ABSTRACT
Eight bidentate NHC/Ru complexes, namely [Ru]-1-[Ru]-8, were designed and prepared. In particular, [Ru]-2 displayed extraordinary performance even in open air for the dehydrogenative coupling of alcohols and hydroxides. Notably, an unprecedentedly low catalyst loading of 250 ppm and the highest TON of 32 800 and TOF of 3200 until now were obtained.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2019 Tipo de documento: Article
Texto completo
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PubMed Links
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2019 Tipo de documento: Article