High pressure synthesis of a quasi-one-dimensional GdFeO3-type perovskite PrCuO3 with nearly divalent Cu ions.
Chem Commun (Camb)
; 55(61): 8931-8934, 2019 Aug 07.
Article
em En
| MEDLINE
| ID: mdl-31290901
ABSTRACT
A new perovskite-type cuprate PrCuO3 has been synthesized by high-pressure oxygen annealing. Synchrotron X-ray powder diffraction and absorption spectroscopy revealed that PrCuO3 crystallizes in the GdFeO3-type structure with cooperative Jahn-Teller distortion, forming one-dimensional chains of corner-shared CuO4 plaquettes with nearly divalent Cu ions.
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MEDLINE
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En
Ano de publicação:
2019
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Article