Amine-Catalyzed Decarboxylative Aldol Reaction of ß-Ketocarboxylic Acids with Trifluoropyruvates.

Kawanishi, Ryouta; Hattori, Shinya; Iwasa, Seiji; Shibatomi, Kazutaka

Kawanishi, Ryouta; Hattori, Shinya; Iwasa, Seiji; Shibatomi, Kazutaka.

Afiliação

Kawanishi R; Department of Applied Chemistry and Life Science, Toyohashi University of Technology, 1-1 Hibarigaoka, Tempaku-cho, Toyohashi 441-8580, Japan.
Hattori S; Department of Applied Chemistry and Life Science, Toyohashi University of Technology, 1-1 Hibarigaoka, Tempaku-cho, Toyohashi 441-8580, Japan.
Iwasa S; Department of Applied Chemistry and Life Science, Toyohashi University of Technology, 1-1 Hibarigaoka, Tempaku-cho, Toyohashi 441-8580, Japan.
Shibatomi K; Department of Applied Chemistry and Life Science, Toyohashi University of Technology, 1-1 Hibarigaoka, Tempaku-cho, Toyohashi 441-8580, Japan. shiba@chem.tut.ac.jp.

Molecules ; 24(15)2019 Jul 30.

Article em En | MEDLINE | ID: mdl-31366138

Assuntos

Aldeídos/química; Ácidos Carboxílicos/química; Alcaloides de Cinchona/química; Ácido Pirúvico/análogos & derivados; Aminas/química; Catálise; Fluoretos/química; Estrutura Molecular; Estereoisomerismo

Palavras-chave

aldol reaction; chiral amine catalyst; cinchona alkaloids; decarboxylation; enantioselective synthesis; trifluoromethyl compounds

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Texto completo: 1 Base de dados: MEDLINE Assunto principal: Ácidos Carboxílicos / Alcaloides de Cinchona / Ácido Pirúvico / Aldeídos Idioma: En Ano de publicação: 2019 Tipo de documento: Article

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