Solvent-Free Chemoselective Hydrogenation of Squalene to Squalane.
ACS Omega
; 2(7): 3989-3996, 2017 Jul 31.
Article
em En
| MEDLINE
| ID: mdl-31457702
ABSTRACT
Squalene is selectively and entirely converted into squalane over the spherical sol-gel-entrapped Pd catalyst SiliaCat Pd(0) under solvent-free and mild reaction conditions of 3 bar H2 and 70 °C. The catalyst was reused successfully in eight consecutive cycles, with palladium leaching values <2 ppm, opening the route to sustainable and less-expensive hydrogenation of phytosqualene with important sustainability consequences.
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MEDLINE
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En
Ano de publicação:
2017
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Article