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Selenoamides modulate dipole-dipole interactions in hydrogen bonded supramolecular polymers of 1,3,5-substituted benzenes.
Berrocal, José Augusto; Mabesoone, Mathijs F J; García Iglesias, Miguel; Huizinga, Alex; Meijer, E W; Palmans, Anja R A.
Afiliação
  • Berrocal JA; Institute for Complex Molecular Systems, Eindhoven University of Technology, P. O Box 513, 5600 MB Eindhoven, The Netherlands. a.palmans@tue.nl e.w.meijer@tue.nl.
  • Mabesoone MFJ; Institute for Complex Molecular Systems, Eindhoven University of Technology, P. O Box 513, 5600 MB Eindhoven, The Netherlands. a.palmans@tue.nl e.w.meijer@tue.nl.
  • García Iglesias M; Institute for Complex Molecular Systems, Eindhoven University of Technology, P. O Box 513, 5600 MB Eindhoven, The Netherlands. a.palmans@tue.nl e.w.meijer@tue.nl and Department of Organic Chemistry, Universidad Autónoma de Madrid (UAM), Calle Francisco Tomás y Valiente, 7, 28049 Madrid, Spain and IM
  • Huizinga A; Institute for Complex Molecular Systems, Eindhoven University of Technology, P. O Box 513, 5600 MB Eindhoven, The Netherlands. a.palmans@tue.nl e.w.meijer@tue.nl.
  • Meijer EW; Institute for Complex Molecular Systems, Eindhoven University of Technology, P. O Box 513, 5600 MB Eindhoven, The Netherlands. a.palmans@tue.nl e.w.meijer@tue.nl.
  • Palmans ARA; Institute for Complex Molecular Systems, Eindhoven University of Technology, P. O Box 513, 5600 MB Eindhoven, The Netherlands. a.palmans@tue.nl e.w.meijer@tue.nl.
Chem Commun (Camb) ; 55(99): 14906-14909, 2019 Dec 25.
Article em En | MEDLINE | ID: mdl-31769447
ABSTRACT
We report the synthesis and self-assembly behavior of a chiral C3-symmetrical benzene-tricarboselenoamide. The introduction of the selenoamide moiety enhances the dipolar character of the supramolecular interaction and confers a remarkable thermal stability to the supramolecular polymers obtained.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2019 Tipo de documento: Article
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2019 Tipo de documento: Article