Formation kinetics of Maillard reaction intermediates from glycine-ribose system and improving Amadori rearrangement product through controlled thermal reaction and vacuum dehydration.
Food Chem
; 311: 125877, 2020 May 01.
Article
em En
| MEDLINE
| ID: mdl-31780222
ABSTRACT
Amadori rearrangement product (ARP) is an ideal flavor precursor. The formation kinetics of ARP from glycine-ribose system, 3-deoxyribosone (3-DR) and 1-deoxyribosone (1-DR) were evaluated, and then controlled thermal reaction (CTR) coupled with vacuum dehydration was proposed to improve the ARP yield. As key factors controlling the formation of byproducts, CTR temperature and time were optimized as 100 °C, 60 min based on the formation kinetics of the ARP and deoxyribosones. Vacuum dehydration was further used to increase the ARP yield from 0.77% to 64.50%, which was improved by 82.8 times, while 3-DR and 1-DR yield increased only by 1.5 and 3.7 times, respectively. The formation of ARP was the dominant reaction during vacuum dehydration. Under optimal conditions, CTR coupled with vacuum dehydration was an effective method to control byproducts formation and improve the ARP yield simultaneously. This method may offer a potential application in flavor enhancement of light-color food.
Palavras-chave
1-Deoxyribosone; 1-Deoxyribosone (PubChem CID: no items); 3-Deoxyribosone; 3-Deoxyribosone (PubChem CID: no items); Amadori rearrangement product; Controlled thermal reaction; Diacetyl (PubChem CID: 650); Formation kinetics; Glyoxal (PubChem CID: 7860); Methylglyoxal (PubChem CID: 880); N-(1-Deoxy-α-d-ribulos-1-yl)-glycine (PubChem CID: no items); Synergistic vacuum dehydration; d-Ribose (PubChem CID: 10975657); l-Glycine (PubChem CID: 750)
Texto completo:
1
Base de dados:
MEDLINE
Assunto principal:
Ribose
/
Reação de Maillard
/
Glicina
Idioma:
En
Ano de publicação:
2020
Tipo de documento:
Article