Fused-Pentagon Isomers of C60 Fullerene Isolated as Chloro and Trifluoromethyl Derivatives.
Chemistry
; 26(11): 2338-2341, 2020 Feb 21.
Article
em En
| MEDLINE
| ID: mdl-31849115
ABSTRACT
The carbon cage of buckminsterfullerene Ih -C60 , which obeys the Isolated-Pentagon Rule (IPR), can be transformed to non-IPR cages in the course of high-temperature chlorination of C60 or C60 Cl30 with SbCl5 . The non-IPR chloro derivatives were isolated chromatographically (HPLC) and characterized crystallographically as 1809 C60 Cl16 , 1810 C60 Cl24 , and 1805 C60 Cl24 , which contain, respectively two, four, and four pairs of fused pentagons in the carbon cage. High-temperature trifluoromethylation of the chlorination products with CF3 I afforded a non-IPR CF3 derivative, 1807 C60 (CF3 )12 , which contains four pairs of fused pentagons in the carbon cage. Addition patterns of non-IPR chloro and CF3 derivatives were compared and discussed in terms of the formation of stabilizing local substructures on fullerene cages. A detailed scheme of the experimentally confirmed non-IPR C60 isomers obtained by Stone-Wales cage transformations is presented.
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MEDLINE
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2020
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Article