A heterobimetallic cumulenic µ-carbido complex.
Chem Commun (Camb)
; 56(15): 2356-2359, 2020 Feb 20.
Article
em En
| MEDLINE
| ID: mdl-31993588
ABSTRACT
The reaction [W(CSe)(CO)2(Tp*)]NEt4 (Tp* = hydrotris(dimethylpyrazolyl)borate) with N-methyl-N-nitroso-4-toluenesulfonamide affords the nitrosyl complex [W(CSe)(CO)(NO)(Tp*)] which on treatment with excess [Re(THF)(CO)2(η-C5H5)] affords the cumuenic µ-carbido complex [WRe(µ-C)(CO)3(NO)(Tp*)(η-C5H5)] in addition to the µ-selenido complex [Re2(µ-Se)(CO)4(η-C5H5)2].
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MEDLINE
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En
Ano de publicação:
2020
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Article