A Diiron Hydrogenase Mimic Featuring a 1,2,3-Triazolylidene.
Chimia (Aarau)
; 74(6): 499-503, 2020 Jun 24.
Article
em En
| MEDLINE
| ID: mdl-32560757
ABSTRACT
A novel complex featuring a mesoionic carbene [Fe2(CO)5(trz)(µ-pdt)] (1) (trz = 1-phenyl-l,3-methyl,4-butyl-1,2,3-triazol-5-ylidene), was synthesized and spectroscopically and structurally characterized. The reductive behaviour of this compound in the presence and in the absence of acid (CH3CO2H) was examined by cyclic voltammetry (CV) that revealed the lack of efficient activity towards proton reduction.
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Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2020
Tipo de documento:
Article