DMAP and PivOH-promoted amination/allenization reaction.

Zhang, Bo-Sheng; Li, Yuke; Gou, Xue-Ya; Zhang, Zhe; An, Yang; Wang, Xin-Gang; Liang, Yong-Min

Zhang, Bo-Sheng; Li, Yuke; Gou, Xue-Ya; Zhang, Zhe; An, Yang; Wang, Xin-Gang; Liang, Yong-Min.

Afiliação

Zhang BS; College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, Gansu 730070, China.

Chem Commun (Camb) ; 56(64): 9202-9205, 2020 Aug 18.

Article em En | MEDLINE | ID: mdl-32661547

ABSTRACT

ABSTRACT

This report described the first DMAP and PivOH-promoted ortho-C-H amination and ipso-allenization reaction of iodobenzenes realized by Pd/norbornene cooperative catalysis. Based on control experiments and DFT calculations, we speculated that the three ligands have different functions and mechanism paths in the reaction.

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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2020 Tipo de documento: Article

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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2020 Tipo de documento: Article