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Synthesis and Exfoliation of a New Layered Mesoporous Zr-MOF Comprising Hexa- and Dodecanuclear Clusters as Well as a Small Organic Linker Molecule.
Leubner, Sebastian; Bengtsson, Viktor E G; Synnatschke, Kevin; Gosch, Jonas; Koch, Alexander; Reinsch, Helge; Xu, Hongyi; Backes, Claudia; Zou, Xiaodong; Stock, Norbert.
Afiliação
  • Leubner S; Institute of Inorganic Chemistry, University of Kiel, Max-Eyth Strasse 2, 24118 Kiel, Germany.
  • Bengtsson VEG; Department of Materials and Environmental Chemistry, Stockholm University, SE-106 91 Stockholm, Sweden.
  • Synnatschke K; Institute of Physical Chemistry, Heidelberg University, Im Neuenheimer Feld 253, 69120 Heidelberg, Germany.
  • Gosch J; Institute of Inorganic Chemistry, University of Kiel, Max-Eyth Strasse 2, 24118 Kiel, Germany.
  • Koch A; Institute of Inorganic Chemistry, University of Kiel, Max-Eyth Strasse 2, 24118 Kiel, Germany.
  • Reinsch H; Institute of Inorganic Chemistry, University of Kiel, Max-Eyth Strasse 2, 24118 Kiel, Germany.
  • Xu H; Department of Materials and Environmental Chemistry, Stockholm University, SE-106 91 Stockholm, Sweden.
  • Backes C; Institute of Physical Chemistry, Heidelberg University, Im Neuenheimer Feld 253, 69120 Heidelberg, Germany.
  • Zou X; Department of Materials and Environmental Chemistry, Stockholm University, SE-106 91 Stockholm, Sweden.
  • Stock N; Institute of Inorganic Chemistry, University of Kiel, Max-Eyth Strasse 2, 24118 Kiel, Germany.
J Am Chem Soc ; 142(37): 15995-16000, 2020 Sep 16.
Article em En | MEDLINE | ID: mdl-32820922
ABSTRACT
A new layered mesoporous Zr-MOF of composition [Zr30O20(OH)26(OAc)18L18] was synthesized by employing 5-acetamidoisophthalic acid (H2L) using acetic acid as the solvent. The new MOF, denoted as CAU-45, exhibits a honeycomb structure of stacked layers which comprise both hexa- and dodecanucelar zirconium clusters. Its structure was solved from submicrometer-sized crystals by continuous rotation electron diffraction (cRED). Liquid phase exfoliation and size selection were successfully performed on the material.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2020 Tipo de documento: Article
Texto completo
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2020 Tipo de documento: Article