Cobalt-catalyzed carboxylation of aryl and vinyl chlorides with CO2.
Chem Commun (Camb)
; 56(92): 14416-14419, 2020 Nov 19.
Article
em En
| MEDLINE
| ID: mdl-33146176
ABSTRACT
The transition-metal-catalyzed carboxylation of aryl and vinyl chlorides with CO2 is rarely studied, and has been achieved only with a Ni catalyst or combination of palladium and photoredox. In this work, the cobalt-catalyzed carboxylation of aryl and vinyl chlorides and bromides with CO2 has been developed. These transformations proceed under mild conditions and exhibit a broad substrate scope, affording the corresponding carboxylic acids in good to high yields.
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MEDLINE
Idioma:
En
Ano de publicação:
2020
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Article