Facile cyclization of sodium aminodiboranate to construct a boron-nitrogen-hydrogen ring.
Dalton Trans
; 49(46): 16662-16666, 2020 Dec 08.
Article
em En
| MEDLINE
| ID: mdl-33196721
ABSTRACT
A facile and efficient cyclization of sodium aminodiboranate to construct a boron-nitrogen-hydrogen ring is presented. This new strategy can be developed into a general method to prepare aminodiborane and its derivatives. Theoretical calculations show that a one-step cyclization mechanism is favored, where the dihydrogen bond plays an important role.
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MEDLINE
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En
Ano de publicação:
2020
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Article