Dual-carbon coupled Co5.47N composites for capacitive lithium-ion storage.
J Colloid Interface Sci
; 587: 192-201, 2021 Apr.
Article
em En
| MEDLINE
| ID: mdl-33360892
ABSTRACT
Transition metal nitrides are of great interest as potential anodes for lithium-ion batteries (LIBs) owing to their high theoretical capacity. However, poor cycling stability and rate performance greatly hinder their practical applications. To better alleviate these problems, a unique 3D hierarchical nanocomposite constructed by dual carbon-coated Co5.47N nano-grains wrapped with carbon and reduced graphene oxide (Co5.47N@C@rGO) was synthesized through one-step simultaneous nitridation and carbonization of zeolitic imidazolate frameworks@GO precursor. The 3D hierarchical Co5.47N@C@rGO composite can combine the good conductivity and mechanical strength of rGO and a high theoretical capacity of Co5.47N. When explored as anode material for LIBs, Co5.47N@C@rGO exhibits a high reversible capacity of ~860 mAh g-1 at a current density of 1.0 A g-1 after 500 cycles and excellent high-rate capability (665 and 573 mAh g-1 at current densities of 3.2 and 6.4 A g-1, respectively). The excellent electrochemical performance of Co5.47N@C@rGO can be ascribed to its hierarchically porous structure and the synergistic effect between Co5.47N nano-grains and rGO.
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MEDLINE
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En
Ano de publicação:
2021
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Article