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Self-sorting of porous Cu4L2L'2 metal-organic cages composed of isomerisable ligands.
Markwell-Heys, Adrian W; Schneider, Matthew L; Madridejos, Jenica Marie L; Metha, Gregory F; Bloch, Witold M.
Afiliação
  • Markwell-Heys AW; Department of Chemistry, The University of Adelaide, Adelaide 5005, Australia. witold.bloch@adelaide.edu.au.
  • Schneider ML; Department of Chemistry, The University of Adelaide, Adelaide 5005, Australia. witold.bloch@adelaide.edu.au.
  • Madridejos JML; Department of Chemistry, The University of Adelaide, Adelaide 5005, Australia. witold.bloch@adelaide.edu.au.
  • Metha GF; Department of Chemistry, The University of Adelaide, Adelaide 5005, Australia. witold.bloch@adelaide.edu.au.
  • Bloch WM; Department of Chemistry, The University of Adelaide, Adelaide 5005, Australia. witold.bloch@adelaide.edu.au.
Chem Commun (Camb) ; 57(23): 2915-2918, 2021 Mar 18.
Article em En | MEDLINE | ID: mdl-33616581
ABSTRACT
We report the self-sorting of a dynamic combinatorial library (DCL) of metal-organic cages composed of a rotationally isomerisable ligand. Convergence of the DCL occurs upon crystallisation and leads to low-symmetry Cu4L2L'2 cages that display differing porosities based on their overall shape and ligand configuration.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2021 Tipo de documento: Article
Texto completo
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2021 Tipo de documento: Article