Your browser doesn't support javascript.
loading
Synthesis of Enynic and Allenic Orthoesters via Defluoromethoxylation of 2-Trifluoromethyl-1,3-enynes.
Dai, Dong-Ting; Xu, Jian-Lin; Chen, Zhi-Yuan; Wang, Zi-Lu; Xu, Yun-He.
Afiliação
  • Dai DT; Department of Chemistry, University of Science and Technology of China, Hefei 230026, P. R. China.
  • Xu JL; Department of Chemistry, University of Science and Technology of China, Hefei 230026, P. R. China.
  • Chen ZY; Department of Chemistry, University of Science and Technology of China, Hefei 230026, P. R. China.
  • Wang ZL; Department of Chemistry, University of Science and Technology of China, Hefei 230026, P. R. China.
  • Xu YH; Department of Chemistry, University of Science and Technology of China, Hefei 230026, P. R. China.
Org Lett ; 23(5): 1898-1903, 2021 03 05.
Article em En | MEDLINE | ID: mdl-33624501
ABSTRACT
In this protocol, the chemoselective defluoromethoxylation reactions of 2-trifluoromethyl-1,3-enynes were developed. The enynic and allenic orthoesters were selectively produced in good to excellent yields via multiple substitution processes under mild reaction conditions, respectively. The enynic orthoester products were proved capable of acting as efficient "platform molecules" to access various functionalized allenyl compounds.
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2021 Tipo de documento: Article
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2021 Tipo de documento: Article