Your browser doesn't support javascript.
loading
Palladium-Catalyzed Linear Hydrothiocarbonylation of Unactivated Terminal Alkenes: Synthesis of Aliphatic Thioesters.
Yu, Wangzhi; Han, Jian; Fang, Dongmei; Wang, Min; Liao, Jian.
Afiliação
  • Yu W; Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu 610041, P.R. China.
  • Han J; University of Chinese Academy of Sciences, Beijing 100049, P.R. China.
  • Fang D; College of Chemical Engineering, Sichuan University, Chengdu 610065, China.
  • Wang M; Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu 610041, P.R. China.
  • Liao J; University of Chinese Academy of Sciences, Beijing 100049, P.R. China.
Org Lett ; 23(7): 2482-2487, 2021 Apr 02.
Article em En | MEDLINE | ID: mdl-33711895
A Pd-catalyzed hydrothiocarbonylation of unactivated terminal alkenes is presented. According to this protocol, aliphatic thioesters were synthesized with exclusive linear selectivity under mild reaction conditions. Good to excellent yields (up to 91% yield), broad substrate scope, broad functional group tolerance, and utility of the method demonstrated the advantages of this protocol.

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2021 Tipo de documento: Article

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2021 Tipo de documento: Article