General Synthesis of Amorphous PdM (M = Cu, Fe, Co, Ni) Alloy Nanowires for Boosting HCOOH Dehydrogenation.
Nano Lett
; 21(8): 3458-3464, 2021 Apr 28.
Article
em En
| MEDLINE
| ID: mdl-33825464
ABSTRACT
Noble metal-based nanomaterials with amorphous structures are promising candidates for developing efficient electrocatalysts. However, their synthesis remains a significant challenge, especially under mild conditions. In this paper, we report a general strategy for preparing amorphous PdM nanowires (a-PdM NWs, M = Fe, Co, Ni, and Cu) at low temperatures by exploiting glassy non-noble metal (M) nuclei generated by special ligand adsorption as the amorphization dictator. When evaluated as electrocatalysts toward formic acid oxidation, a-PdCu NWs can deliver the mass and specific activities as high as 2.93 A/mgPd and 5.33 mA/cm2, respectively; these are the highest values for PdCu-based catalysts reported thus far, far surpassing the crystalline-dominant counterparts and commercial Pd/C. Theoretical calculations suggest that the outstanding catalytic performance of a-PdCu NWs arises from the amorphization-induced high surface reactivity, which can efficiently activate the chemically stable C-H bond and thereby significantly facilitate the dissociation of HCOOH.
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MEDLINE
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Ano de publicação:
2021
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Article