Recovery of sulfur from sulfur-rich filter cakes in a rotary kiln: Process optimization.
Waste Manag
; 126: 567-577, 2021 May 01.
Article
em En
| MEDLINE
| ID: mdl-33864985
ABSTRACT
In this work, sulfur recovery from sulfur-rich wastes deriving from sulfur filtration was investigated through laboratory experiments and full-scale tests in an industrial combustion rotary kiln, where elemental sulfur is converted to SO2 in a sulfuric acid production plant. Phase equilibria experiments carried out in the temperature range 1100-1400 °C and industrial scale tests demonstrated that temperature is the most important operating parameter in determining the recovery efficiency and the plant operability. The full-scale tests performed on the rotary kiln showed that, at operating temperatures around 1200 °C, a continuous sulfur recovery from the filter cakes was obtained with an average efficiency of 87% and a consequent reduction of about 70% of the solid waste material to be disposed as inert in landfills or used in cement/glass industries. The efficiency of sulfur recovery increases with the increasing operating temperature but, above 1300 °C, the melting of the residual Ca-Fe-Al-silicate phase and the eventual recrystallization at the kiln refractory walls occurred, causing a forced plant shutdown. The chemical-physical interaction between the sulfur-rich filter cake and different refractory materials was further investigated in the temperature range 1100-1300 °C. At the recommended operation temperatures of 1100-1200 °C, the interaction between the refractory material and the combustion ashes is negligible for all tested materials. Nonetheless, the use of Fe- and Cr-free refractory materials for the internal lining of the kiln must be preferred to minimize the deposition/adhesion of Ca-Fe-Al-silicates derived from combustion over long-term operation.
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MEDLINE
Assunto principal:
Resíduos Sólidos
/
Materiais de Construção
Idioma:
En
Ano de publicação:
2021
Tipo de documento:
Article