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Creating porosity in a trianglimine macrocycle by heterochiral pairing.
He, Donglin; Clowes, Rob; Little, Marc A; Liu, Ming; Cooper, Andrew I.
Afiliação
  • He D; Materials Innovation Factory and Chemistry Department, University of Liverpool, Liverpool, L7 3NY, UK. aicooper@liverpool.ac.uk.
  • Clowes R; Materials Innovation Factory and Chemistry Department, University of Liverpool, Liverpool, L7 3NY, UK. aicooper@liverpool.ac.uk.
  • Little MA; Materials Innovation Factory and Chemistry Department, University of Liverpool, Liverpool, L7 3NY, UK. aicooper@liverpool.ac.uk.
  • Liu M; Materials Innovation Factory and Chemistry Department, University of Liverpool, Liverpool, L7 3NY, UK. aicooper@liverpool.ac.uk.
  • Cooper AI; Materials Innovation Factory and Chemistry Department, University of Liverpool, Liverpool, L7 3NY, UK. aicooper@liverpool.ac.uk.
Chem Commun (Camb) ; 57(50): 6141-6144, 2021 Jun 22.
Article em En | MEDLINE | ID: mdl-34042126
ABSTRACT
Macrocycles are usually non-porous or barely porous in the solid-state because of their small intrinsic cavity sizes and tendency to close-pack. Here, we use a heterochiral pairing strategy to introduce porosity in a trianglimine macrocycle, by co-crystallising two macrocycles with opposing chiralities. The stable racemic trianglimine crystal contains an interconnected pore network that has a Brunauer-Emmett-Teller (BET) surface area of 355 m2 g-1.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2021 Tipo de documento: Article
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2021 Tipo de documento: Article