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Palladium-Catalyzed C-H Allylation of Electron-Deficient Polyfluoroarenes with gem-Difluorinated Cyclopropanes.
Zhou, Ping-Xin; Yang, Xiaozhe; Wang, Jia; Ge, Chunpo; Feng, Wang; Liang, Yong-Min; Zhang, Yu.
Afiliação
  • Zhou PX; School of Basic Medical Sciences, Xinxiang Medical University, Xinxiang, 453000, P. R. China.
  • Yang X; School of Basic Medical Sciences, Xinxiang Medical University, Xinxiang, 453000, P. R. China.
  • Wang J; School of Basic Medical Sciences, Xinxiang Medical University, Xinxiang, 453000, P. R. China.
  • Ge C; School of Basic Medical Sciences, Xinxiang Medical University, Xinxiang, 453000, P. R. China.
  • Feng W; School of Basic Medical Sciences, Xinxiang Medical University, Xinxiang, 453000, P. R. China.
  • Liang YM; State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, 730000, P. R. China.
  • Zhang Y; School of Basic Medical Sciences, Xinxiang Medical University, Xinxiang, 453000, P. R. China.
Org Lett ; 23(12): 4920-4924, 2021 06 18.
Article em En | MEDLINE | ID: mdl-34085517
ABSTRACT
A palladium-catalyzed C-H allylation of electron-deficient polyfluoroarenes with gem-difluorinated cyclopropanes is reported. It provides a useful and facile approach to 2-fluoroallylic polyfluoroarenes in moderate to excellent yields with high Z-selectivity. In addition, this new approach has good functional group compatibility and broad substrate scope.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2021 Tipo de documento: Article
Texto completo
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PubMed Links
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2021 Tipo de documento: Article