Rh-catalyzed tunable defluorinative borylation.
Chem Commun (Camb)
; 57(58): 7124-7127, 2021 Jul 20.
Article
em En
| MEDLINE
| ID: mdl-34179910
ABSTRACT
Described herein is a Rh-catalyzed tunable defluorinative borylation of allylic gem-difluorides to provide allylborylated monofluoroalkenes or homoallylborylated monofluoroalkenes with excellent Z/E selectivities. Completely different reaction paths were observed by slightly changing the reaction conditions. Allylborylated monofluoroalkenes were further converted into dihydroxyl-containing monofluoroalkenes.
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MEDLINE
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En
Ano de publicação:
2021
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Article