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Rh-catalyzed tunable defluorinative borylation.
Hao, Fei; Shang, Xueyun; Liu, Zhenwei; Zhang, He; Lin, Jin-Hong; Xiao, Ji-Chang.
Afiliação
  • Hao F; Shandong Provincial Key Laboratory of Molecular Engineering, Qilu University of Technology-Shandong Academy of Science, Ji'nan 250353, China and Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences
  • Shang X; Shandong Provincial Key Laboratory of Molecular Engineering, Qilu University of Technology-Shandong Academy of Science, Ji'nan 250353, China.
  • Liu Z; Shandong Provincial Key Laboratory of Molecular Engineering, Qilu University of Technology-Shandong Academy of Science, Ji'nan 250353, China.
  • Zhang H; Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China. zhanghe07@gmail.com jlin@sioc.ac.cn jchxiao@sioc.ac.cn.
  • Lin JH; Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China. zhanghe07@gmail.com jlin@sioc.ac.cn jchxiao@sioc.ac.cn and Department of Chemistry, Innovative Drug
  • Xiao JC; Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China. zhanghe07@gmail.com jlin@sioc.ac.cn jchxiao@sioc.ac.cn.
Chem Commun (Camb) ; 57(58): 7124-7127, 2021 Jul 20.
Article em En | MEDLINE | ID: mdl-34179910
ABSTRACT
Described herein is a Rh-catalyzed tunable defluorinative borylation of allylic gem-difluorides to provide allylborylated monofluoroalkenes or homoallylborylated monofluoroalkenes with excellent Z/E selectivities. Completely different reaction paths were observed by slightly changing the reaction conditions. Allylborylated monofluoroalkenes were further converted into dihydroxyl-containing monofluoroalkenes.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2021 Tipo de documento: Article
Texto completo
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2021 Tipo de documento: Article