Second-Generation Light-Fueled Supramolecular Pump.
J Am Chem Soc
; 143(29): 10890-10894, 2021 07 28.
Article
em En
| MEDLINE
| ID: mdl-34282901
ABSTRACT
We describe the modular design of a pseudorotaxane-based supramolecular pump and its photochemically driven autonomous nonequilibrium operation in a dissipative regime. These properties derive from careful engineering of the energy maxima and minima along the threading coordinate and their light-triggered modulation. Unlike its precursor, this second-generation system is amenable to functionalization for integration into more complex devices.
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MEDLINE
Idioma:
En
Ano de publicação:
2021
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Article