Organic guest molecule induced ultrafast breathing of an epitaxially grown metal-organic framework on a self-assembled monolayer.
Chem Commun (Camb)
; 57(79): 10158-10161, 2021 Oct 05.
Article
em En
| MEDLINE
| ID: mdl-34505597
ABSTRACT
We report epitaxially grown new two-dimensional metal-organic framework (MOF) thin films on a self-assembled monolayer (SAM). We fabricated these epitaxial thin-films using stepwise layer-by-layer seeding followed by solvothermal treatment. The MOF thin films exhibit ultrafast structural flexibility (through breathing) compared to their bulk samples upon uptake of organic guest molecules.
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MEDLINE
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En
Ano de publicação:
2021
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Article