Characteristic flavor formation of thermally processed N-(1-deoxy-α-d-ribulos-1-yl)-glycine: Decisive role of additional amino acids and promotional effect of glyoxal.
Food Chem
; 371: 131137, 2022 Mar 01.
Article
em En
| MEDLINE
| ID: mdl-34562777
ABSTRACT
The role of amino acids and α-dicarbonyls in the flavor formation of Amadori rearrangement product (ARP) during thermal processing was investigated. Comparisons of the volatile compounds and their concentrations when N-(1-deoxy-α-d-ribulos-1-yl)-glycine reacted with different amino acids or glyoxal (GO) at 100 °C were executed. Additional amino acids, such as glycine (Gly), in ARP models contributed to the diversity of furanoids by the chain elongation of the derived formaldehyde. Whereas the monoanion of additional glutamic acid acted as nucleophile, favored 2-ethyl-3,5-dimethylpyrazine and 2,5-dimethylpyrazine formation; the nonionized amino group of additional lysine were involved in α-dicarbonyls formation, causing pyrazine and methylpyrazine accumulation in the ARP model. Moreover, the high dosage and pH stabilization of additional GO probably promoted the ARP degradation and deoxyosones retro-aldol cleavage, resulting in methylpyrazine rather than furanoids formation. The present work provided the guidance for the controlled flavor formation of ARP in industrial application.
Palavras-chave
Amadori rearrangement product; Flavor; Furanoids; Pyrazines; Strecker degradation; d-ribose (PubChem CID: 10975657); l-cysteine (PubChem CID: 5862); l-glutamic acid (PubChem CID: 33032).; l-glycine (PubChem CID: 750); l-histidine (PubChem CID: 6274); l-lysine (PubChem CID: 5962); l-methionine (PubChem CID: 6137); α-Dicarbonyls
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MEDLINE
Assunto principal:
Aminoácidos
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Idioma:
En
Ano de publicação:
2022
Tipo de documento:
Article