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Synthesis, characterization, and theoretical analysis of a plutonyl phosphine oxide complex.
Windorff, Cory J; Beltran-Leiva, Maria J; Albrecht-Schönzart, Thomas E; Bai, Zhuanling; Celis-Barros, Cristian; Goodwin, Conrad A P; Huffman, Zachary; McKinnon, Noah C; Sperling, Joseph M.
Afiliação
  • Windorff CJ; Department of Chemistry and Biochemistry, Florida State University, 95 Chieftan Way, RM. 118 DLC, Tallahassee, Florida 32306, USA. ccelisbarros@fsu.edu.
  • Beltran-Leiva MJ; Department of Chemistry and Biochemistry, New Mexico State University, MSC 3C, PO Box 3001, Las Cruces, NM 88003, USA. windorff@nmsu.edu.
  • Albrecht-Schönzart TE; Department of Chemistry and Biochemistry, Florida State University, 95 Chieftan Way, RM. 118 DLC, Tallahassee, Florida 32306, USA. ccelisbarros@fsu.edu.
  • Bai Z; Department of Chemistry and Biochemistry, Florida State University, 95 Chieftan Way, RM. 118 DLC, Tallahassee, Florida 32306, USA. ccelisbarros@fsu.edu.
  • Celis-Barros C; Department of Chemistry and Biochemistry, Florida State University, 95 Chieftan Way, RM. 118 DLC, Tallahassee, Florida 32306, USA. ccelisbarros@fsu.edu.
  • Goodwin CAP; Department of Chemistry and Biochemistry, Florida State University, 95 Chieftan Way, RM. 118 DLC, Tallahassee, Florida 32306, USA. ccelisbarros@fsu.edu.
  • Huffman Z; Chemistry Division, Los Alamos National Laboratory, Los Alamos, NM 87545, USA.
  • McKinnon NC; Department of Chemistry and Biochemistry, Florida State University, 95 Chieftan Way, RM. 118 DLC, Tallahassee, Florida 32306, USA. ccelisbarros@fsu.edu.
  • Sperling JM; Department of Chemistry and Biochemistry, Florida State University, 95 Chieftan Way, RM. 118 DLC, Tallahassee, Florida 32306, USA. ccelisbarros@fsu.edu.
Dalton Trans ; 50(41): 14537-14541, 2021 Oct 26.
Article em En | MEDLINE | ID: mdl-34635890
The interplay of bond strength and covalency are examined in AnO2Cl2(OPcy3)2 (An = Pu, U) complexes. The synthesis of trans-PuO2Cl2(OPcy3)2, 1-Pu, has been carried out and confirmed by single crystal X-ray diffraction along with UV-vis-NIR, and 31P NMR spectroscopies. Theoretical analysis finds that despite a higher calculated covalency for the Pu-Cl interaction, the Pu-OPcy3 interaction is stronger due to the accumulation of electron density in the interatomic region. The coordination of equatorial ligands slightly decreases the strength of the PuOyl interactions relative to the free gas phase (PuO2)2+ ion.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2021 Tipo de documento: Article
Texto completo
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XML
PubMed Links
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2021 Tipo de documento: Article