Your browser doesn't support javascript.
loading
Synergistic Pd/Cu-catalysed regio- and stereoselective borylation of allenylic carbonates.
Zhang, Wei-Dong; Zou, Jia-Yu; Zhong, Qin; Li, Shi-Sen; Zhao, Jian.
Afiliação
  • Zhang WD; Department of Chemical Engineering, School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China. zq304@njust.edu.cn.
  • Zou JY; Department of Chemical Engineering, School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China. zq304@njust.edu.cn.
  • Zhong Q; Department of Chemical Engineering, School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China. zq304@njust.edu.cn.
  • Li SS; Department of Chemical Engineering, School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China. zq304@njust.edu.cn.
  • Zhao J; Department of Chemical Engineering, School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China. zq304@njust.edu.cn.
Chem Commun (Camb) ; 58(7): 1037-1040, 2022 Jan 20.
Article em En | MEDLINE | ID: mdl-34951424
ABSTRACT
A simple Pd/Cu-catalyzed borylation of allenylic carbonates with B2Pin2 was developed using a cheap P(OEt)3 ligand. Under mild neutral conditions, 2-boryl 1,3-butadienes were obtained selectively in moderate to high yields. Furthermore, the use of different diboron reagents was also feasible in the reaction.
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2022 Tipo de documento: Article
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2022 Tipo de documento: Article