Solvothermal conversion of spent aromatic waste to ethyl glucosides.

ABSTRACT

On-farm extraction of commercially important essential oil from aromatic crops generates huge spent aromatic waste. This massive waste is often disposed in the unregulated landfills or burned in the open air to vacate the fields. Hence, a new method for processing of aromatic spent waste has been developed to obtain platform chemicals, such as, xylose and ethyl glucosides. The thermochemical liquefaction of acid pre-treated palmarosa (cymbopogon martini) biomass furnished a mixture of ethyl glucopyranosides in good yield (∼17 wt% relative to biomass) and selectivity (∼77%) by heating with p-cymen-2-sulphonic acid (p-CSA) in the presence of ethanol as a solvent. The detection, quantification and isolation of ethyl glucosides may provide a new application of spent aromatic biomass for use as a feed stock in the production of value added chemicals.