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Silver-catalyzed monofluoroalkylation of heteroarenes with α-fluorocarboxylic acids: an insight into the solvent effect.
Guo, Chunfang; Liu, Zhaolong; Li, Xiangye; Han, Xuliang; Li, Yueyun; Liu, Hui; Zhang, Lizhi; Li, Xinjin; Dong, Yunhui.
Afiliação
  • Guo C; College of Chemistry and Chemical Engineering, Shandong University of Technology, 266 West Xincun Road, Zibo, 255000, China. lixj@sdut.edu.cn.
  • Liu Z; Shandong Vocational College of Light Industry, Zhoucun Mishan Road, Zibo, 255300, China.
  • Li X; College of Chemistry and Chemical Engineering, Shandong University of Technology, 266 West Xincun Road, Zibo, 255000, China. lixj@sdut.edu.cn.
  • Han X; College of Chemistry and Chemical Engineering, Shandong University of Technology, 266 West Xincun Road, Zibo, 255000, China. lixj@sdut.edu.cn.
  • Li Y; College of Chemistry and Chemical Engineering, Shandong University of Technology, 266 West Xincun Road, Zibo, 255000, China. lixj@sdut.edu.cn.
  • Liu H; College of Chemistry and Chemical Engineering, Shandong University of Technology, 266 West Xincun Road, Zibo, 255000, China. lixj@sdut.edu.cn.
  • Zhang L; College of Chemistry and Chemical Engineering, Shandong University of Technology, 266 West Xincun Road, Zibo, 255000, China. lixj@sdut.edu.cn.
  • Li X; College of Chemistry and Chemical Engineering, Shandong University of Technology, 266 West Xincun Road, Zibo, 255000, China. lixj@sdut.edu.cn.
  • Dong Y; College of Chemistry and Chemical Engineering, Shandong University of Technology, 266 West Xincun Road, Zibo, 255000, China. lixj@sdut.edu.cn.
Chem Commun (Camb) ; 58(8): 1147-1150, 2022 Jan 25.
Article em En | MEDLINE | ID: mdl-34981099
ABSTRACT
A mild and efficient method for direct C-H monofluoroalkylation of heteroarenes with easily accessible and inexpensive α-fluorocarboxylic acids has been developed. This silver-catalyzed reaction affords mono- and bis-monofluoroalkylated heteroarenes in good yields under mild conditions, and the solvent effect on the monofluoroalkylation reaction is discussed in detail.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2022 Tipo de documento: Article
Texto completo
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2022 Tipo de documento: Article