Formation of melanoidins - Aldol reactions of heterocyclic and short-chain Maillard intermediates.
Food Chem
; 380: 131852, 2022 Jun 30.
Article
em En
| MEDLINE
| ID: mdl-34998624
ABSTRACT
In the course of the Maillard reaction, reducing sugars and amino compounds are converted to colorants, whose chemical structures are still mostly unknown. Active methylene compounds like norfuraneol that can initiate aldol condensation reactions are considered as key intermediates in this reaction. The aim of the present study was to characterize color formation of norfuraneol with different carbonyl compounds and to identify the underlying mechanisms of the reaction. Norfuraneol was incubated with methylglyoxal or diacetyl at elevated temperatures and the resulting reaction mixtures were analyzed by means of high-resolution mass spectrometry. It was demonstrated that aldol reactions lead to the formation of heterogeneous carbohydrate-based oligomers, which are likely to contribute to the elevated browning observed in the reaction mixtures. Furthermore, redox reactions were identified as another important part of the reaction, resulting in an increasing number of double bonds in the detected reaction products.
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Base de dados:
MEDLINE
Assunto principal:
Reação de Maillard
/
Aldeídos
Idioma:
En
Ano de publicação:
2022
Tipo de documento:
Article