Multisize particulate matter and volatile organic compounds in arid and semiarid areas of Northwest China.

ABSTRACT

To investigate the chemical components, sources, and interactions of particulate matter (PM) and volatile organic compounds (VOCs), a field campaign was implemented during the spring of 2018 in nine cities in northwestern (NW) China. PM was mainly contributed by organic matter and water-soluble inorganic ions (41% for PM10 and approximately 60% for PM2.5 and PM1). Two typical haze patterns were observed anthropogenic pollution type (AP-type), wherein contributions of sulfate, nitrate, and ammonium (SNA) increased, and dust pollution type (DP-type), wherein contributions of Ca2+ increased and SNA decreased. Source appointment suggested that regional sources contributed close to half to PM2.5 pollution (40% for AP-type and 50% for DP-type). Thus, sources from regional transport are also important for haze and dust pollution. The ranking of VOC concentrations was methanol > acetaldehyde > formic acid + ethanol > acetone. Compared with other cities, there are higher oxygenated VOCs (OVOCs) and lower aromatics in NW China. The relationships between VOCs and PM were discussed. The dominating secondary organic aerosols (SOA) formation potential precursors were C10-aromatics, xylene, and styrene under low-nitrogen oxide (NOx) conditions, and benzene, C10-aromatics, and toluene dominated under high-NOx conditions. The quadratic polynomial was the most suitable fitting model for their correlation, and the results suggested that VOC oxidations explained 6.1-10.8% and 9.9-20.7% of SOA formation under high-NOx and low-NOx conditions, respectively.