Two-dimensional Zr/Hf-hydroxamate metal-organic frameworks.
Chem Commun (Camb)
; 58(22): 3601-3604, 2022 Mar 15.
Article
em En
| MEDLINE
| ID: mdl-35103744
ABSTRACT
Novel two-dimensional kagome metal-organic frameworks with mononuclear Zr4+/Hf4+ nodes chelated by benzene-1,4-dihydroxamate linkers were synthesized. The MOFs, namely SUM-1, are chemically robust and kinetically favorable, as confirmed by theoretical and experimental studies. SUM-1(Zr) can be readily made into large (â¼100 µm) single crystals and nanoplates (â¼50 nm), constituting a versatile MOF platform.
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MEDLINE
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En
Ano de publicação:
2022
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Article