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A stereoselective hydride transfer reaction with contributions from attractive dispersion force control.
Braddock, D Christopher; Limpaitoon, Natnicha; Oliwa, Krzysztof; O'Reilly, Daniel; Rzepa, Henry S; White, Andrew J P.
Afiliação
  • Braddock DC; Department of Chemistry, Imperial College London, Molecular Sciences Research Hub, White City Campus, London W12 0BZ, UK. c.braddock@imperial.ac.uk.
  • Limpaitoon N; Department of Chemistry, Imperial College London, Molecular Sciences Research Hub, White City Campus, London W12 0BZ, UK. c.braddock@imperial.ac.uk.
  • Oliwa K; Department of Chemistry, Imperial College London, Molecular Sciences Research Hub, White City Campus, London W12 0BZ, UK. c.braddock@imperial.ac.uk.
  • O'Reilly D; Department of Chemistry, Imperial College London, Molecular Sciences Research Hub, White City Campus, London W12 0BZ, UK. c.braddock@imperial.ac.uk.
  • Rzepa HS; Department of Chemistry, Imperial College London, Molecular Sciences Research Hub, White City Campus, London W12 0BZ, UK. c.braddock@imperial.ac.uk.
  • White AJP; Department of Chemistry, Imperial College London, Molecular Sciences Research Hub, White City Campus, London W12 0BZ, UK. c.braddock@imperial.ac.uk.
Chem Commun (Camb) ; 58(32): 4981-4984, 2022 Apr 19.
Article em En | MEDLINE | ID: mdl-35322841
ABSTRACT
The experimentally determined stereochemical outcome of an unprecedented hydride transfer from a lithium alkoxide to an aldehyde is reported, as deconvoluted by the combined use of a single enantiomer alkoxide in conjunction with a deuterium label. The stereoselective outcome is consistent with a computationally predicted transition state model stabilised by contributions from attractive dispersion forces.
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Texto completo: 1 Base de dados: MEDLINE Assunto principal: Estereoisomerismo Idioma: En Ano de publicação: 2022 Tipo de documento: Article
Texto completo
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Texto completo: 1 Base de dados: MEDLINE Assunto principal: Estereoisomerismo Idioma: En Ano de publicação: 2022 Tipo de documento: Article