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An investigation of two copper(ii) complexes with a triazole derivative as a ligand: magnetic and catalytic properties.
Petrenko, Yuliia P; Piasta, Karolina; Khomenko, Dmytro M; Doroshchuk, Roman O; Shova, Sergiu; Novitchi, Ghénadie; Toporivska, Yuliya; Gumienna-Kontecka, Elzbieta; Martins, Luísa M D R S; Lampeka, Rostyslav D.
Afiliação
  • Petrenko YP; Department of Chemistry, Taras Shevchenko National University of Kyiv Volodymyrska Street, 64/13 Kyiv 01601 Ukraine dkhomenko@ukr.net.
  • Piasta K; Faculty of Chemistry, University of Wroclaw F. Joliot-Curie 14 50-383 Wroclaw Poland elzbieta.gumienna-kontecka@chem.uni.wroc.pl.
  • Khomenko DM; Department of Chemistry, Taras Shevchenko National University of Kyiv Volodymyrska Street, 64/13 Kyiv 01601 Ukraine dkhomenko@ukr.net.
  • Doroshchuk RO; Department of Chemistry, Taras Shevchenko National University of Kyiv Volodymyrska Street, 64/13 Kyiv 01601 Ukraine dkhomenko@ukr.net.
  • Shova S; "Petru Poni" Institute of Macromolecular Chemistry, Laboratory of Inorganic Polymers Aleea Grigore Ghica Voda No. 41A RO-700487 Iasi Romania.
  • Novitchi G; Laboratoire National des Champs Magnétiques Intenses, UPR CNRS 3228, Université Grenoble-Alpes 25 rue des Martyrs, B.P. 166 38042 Grenoble Cedex 9 France.
  • Toporivska Y; Faculty of Chemistry, University of Wroclaw F. Joliot-Curie 14 50-383 Wroclaw Poland elzbieta.gumienna-kontecka@chem.uni.wroc.pl.
  • Gumienna-Kontecka E; Faculty of Chemistry, University of Wroclaw F. Joliot-Curie 14 50-383 Wroclaw Poland elzbieta.gumienna-kontecka@chem.uni.wroc.pl.
  • Martins LMDRS; Centro de Química Estrutural, Departamento de Engenharia Química, Instituto Superior Técnico, Universidade de Lisboa Av. Rovisco Pais 1049-001 Lisboa Portugal luisammartins@tecnico.ulisboa.pt.
  • Lampeka RD; Department of Chemistry, Taras Shevchenko National University of Kyiv Volodymyrska Street, 64/13 Kyiv 01601 Ukraine dkhomenko@ukr.net.
RSC Adv ; 11(38): 23442-23449, 2021 Jul 01.
Article em En | MEDLINE | ID: mdl-35479774
ABSTRACT
Two new copper(ii) complexes [Cu2(L)2(OAc)2(H2O)2] (1) (L = 3-methyl-5-pyridin-2-yl-1,2,4-triazole) and [CuL2] (2) were prerared and thoroughly studied. The complexes are able to selectively catalyze the oxidation of styrene towards benzaldehyde and of cyclohexane to KA oil. The 2D coordination polymer 1 showed an antiferromagnetic behaviour attributed to the intrachain magnetic coupling.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2021 Tipo de documento: Article
Texto completo
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2021 Tipo de documento: Article