Construction of stable bio-Pd catalysts for environmental pollutant remediation.

ABSTRACT

It has been reported that Pd nanoparticles were a little weak to bind to the dried microbial (yeast) surface, leading to the poor stability of the bio-supported catalysts. The objectives of the study are to construct stable Pd nanocatalysts supported on the dried yeast surface with the help of a tiny amount (<0.1 wt%) of reduced graphene oxide (Pd/yeast/rGO) and apply the catalysts in environmental pollutant remediation. The characterizations of the as-obtained Pd/yeast/rGO catalysts showed that reduced GO could cover Pd/yeast materials and prepare 15-21 nm Pd nanoparticles under acid and base media. The catalytic performance of the Pd/yeast/rGO catalyst was compared with that of control Pd/yeast catalysts without GO. The results revealed the kinetic constant K app in the reduction of 4-nitrophenol of Pd/yeast/rGO catalysts could reach 3.6 × 10-2 s-1 without stirring during the reaction, which was 2.4 times higher than that of Pd/yeast catalysts, and the Pd/yeast/rGO catalysts kept a good stability even after being reused in seven cycles. Furthermore, the catalysts also showed quite good catalytic activities on CO oxidation and decolorization of dye methylene blue (MB). Thus, Pd/yeast/rGO catalysts were proven to be highly active and stable for environmental remediation and have the advantage that they can prevent the loss of noble metals and be prepared conveniently from discarded microorganisms.