Your browser doesn't support javascript.
loading
Simple Benchtop Approach to Polymer Brush Nanostructures Using Visible-Light-Mediated Metal-Free Atom Transfer Radical Polymerization.
Discekici, Emre H; Pester, Christian W; Treat, Nicolas J; Lawrence, Jimmy; Mattson, Kaila M; Narupai, Benjaporn; Toumayan, Edward P; Luo, Yingdong; McGrath, Alaina J; Clark, Paul G; Read de Alaniz, Javier; Hawker, Craig J.
Afiliação
  • Discekici EH; †Department of Chemistry and Biochemistry, ‡Materials Research Laboratory, §Materials Department, and ⊥Department of Chemical Engineering, University of California, Santa Barbara, California 93106, United States.
  • Pester CW; The Dow Chemical Company, Midland, Michigan 48674, United States.
  • Treat NJ; †Department of Chemistry and Biochemistry, ‡Materials Research Laboratory, §Materials Department, and ⊥Department of Chemical Engineering, University of California, Santa Barbara, California 93106, United States.
  • Lawrence J; The Dow Chemical Company, Midland, Michigan 48674, United States.
  • Mattson KM; †Department of Chemistry and Biochemistry, ‡Materials Research Laboratory, §Materials Department, and ⊥Department of Chemical Engineering, University of California, Santa Barbara, California 93106, United States.
  • Narupai B; The Dow Chemical Company, Midland, Michigan 48674, United States.
  • Toumayan EP; †Department of Chemistry and Biochemistry, ‡Materials Research Laboratory, §Materials Department, and ⊥Department of Chemical Engineering, University of California, Santa Barbara, California 93106, United States.
  • Luo Y; The Dow Chemical Company, Midland, Michigan 48674, United States.
  • McGrath AJ; †Department of Chemistry and Biochemistry, ‡Materials Research Laboratory, §Materials Department, and ⊥Department of Chemical Engineering, University of California, Santa Barbara, California 93106, United States.
  • Clark PG; The Dow Chemical Company, Midland, Michigan 48674, United States.
  • Read de Alaniz J; †Department of Chemistry and Biochemistry, ‡Materials Research Laboratory, §Materials Department, and ⊥Department of Chemical Engineering, University of California, Santa Barbara, California 93106, United States.
  • Hawker CJ; The Dow Chemical Company, Midland, Michigan 48674, United States.
ACS Macro Lett ; 5(2): 258-262, 2016 Feb 16.
Article em En | MEDLINE | ID: mdl-35614689
ABSTRACT
The development of an operationally simple, metal-free surface-initiated atom transfer radical polymerization (SI-ATRP) based on visible-light mediation is reported. The facile nature of this process enables the fabrication of well-defined polymer brushes from flat and curved surfaces using a "benchtop" setup that can be easily scaled to four-inch wafers. This circumvents the requirement of stringent air-free environments (i.e., glovebox), and mediation by visible light allows for spatial control on the micron scale, with complex three-dimensional patterns achieved in a single step. This robust approach leads to unprecedented access to brush architectures for nonexperts.
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2016 Tipo de documento: Article
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2016 Tipo de documento: Article