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Visible-Light-Promoted Cross-Coupling of O-Aryl Oximes and Nitrostyrenes to Access Cyanoalkylated Alkenes.
Gao, Jie; Ye, Zhi-Peng; Liu, Yu-Fei; He, Xian-Chen; Guan, Jian-Ping; Liu, Fang; Chen, Kai; Xiang, Hao-Yue; Chen, Xiao-Qing; Yang, Hua.
Afiliação
  • Gao J; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P.R. China.
  • Ye ZP; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P.R. China.
  • Liu YF; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P.R. China.
  • He XC; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P.R. China.
  • Guan JP; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P.R. China.
  • Liu F; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P.R. China.
  • Chen K; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P.R. China.
  • Xiang HY; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P.R. China.
  • Chen XQ; School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang 453007, Henan P.R. China.
  • Yang H; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P.R. China.
Org Lett ; 24(25): 4640-4644, 2022 Jul 01.
Article em En | MEDLINE | ID: mdl-35729079
A photoinduced, photocatalyst-free cyanoalkylation of nitrostyenes was explored, affording a series of cyanoalkylated alkenes in moderate to good yields. Mechanistic studies reveal that an electron donor-acceptor complex formed between O-aryl oximes and DIPEA is presumably involved in this process. The excellent functional group compatibility of this newly designed synthetic protocol allows for cyanoalkylation of structurally varied substrates, which offers an eco-friendly pathway for the assembly of cyanoalkylated alkenes.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2022 Tipo de documento: Article
Texto completo
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2022 Tipo de documento: Article