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Arsolyl-supported intermetallic dative bonding.
Kirk, Ryan M; Hill, Anthony F.
Afiliação
  • Kirk RM; Research School of Chemistry, Australian National University Canberra A.C.T. Australia a,hill@anu.edu.au.
  • Hill AF; Research School of Chemistry, Australian National University Canberra A.C.T. Australia a,hill@anu.edu.au.
Chem Sci ; 13(23): 6830-6835, 2022 Jun 15.
Article em En | MEDLINE | ID: mdl-35774176
ABSTRACT
The first examples of late transition metal η5-arsolyls (L = CO, P(OMe)3; R = Ph, Me, Et, SiMe3; R' = Ph, H, Me, Et, Me) serve as ditopic donors to extraneous metal centres (M = PtII, AuI, HgII) through both conventional As → M and polar-covalent (dative) Co → M interactions.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2022 Tipo de documento: Article
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2022 Tipo de documento: Article