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Molecular Engineering of Sulfur-Bridged Polycyclic Emitters Towards Tunable TADF and RTP Electroluminescence.
Li, Mengke; Xie, Wentao; Cai, Xinyi; Peng, Xiaomei; Liu, Kunkun; Gu, Qing; Zhou, Jiadong; Qiu, Weidong; Chen, Zijian; Gan, Yiyang; Su, Shi-Jian.
Afiliação
  • Li M; State Key Laboratory of Luminescent Materials and Devices and Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Wushan Road 381, Tianhe District, Guangzhou, 510640, Guangdong Province, P. R. China.
  • Xie W; State Key Laboratory of Luminescent Materials and Devices and Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Wushan Road 381, Tianhe District, Guangzhou, 510640, Guangdong Province, P. R. China.
  • Cai X; State Key Laboratory of Luminescent Materials and Devices and Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Wushan Road 381, Tianhe District, Guangzhou, 510640, Guangdong Province, P. R. China.
  • Peng X; State Key Laboratory of Luminescent Materials and Devices and Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Wushan Road 381, Tianhe District, Guangzhou, 510640, Guangdong Province, P. R. China.
  • Liu K; State Key Laboratory of Luminescent Materials and Devices and Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Wushan Road 381, Tianhe District, Guangzhou, 510640, Guangdong Province, P. R. China.
  • Gu Q; State Key Laboratory of Luminescent Materials and Devices and Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Wushan Road 381, Tianhe District, Guangzhou, 510640, Guangdong Province, P. R. China.
  • Zhou J; State Key Laboratory of Luminescent Materials and Devices and Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Wushan Road 381, Tianhe District, Guangzhou, 510640, Guangdong Province, P. R. China.
  • Qiu W; State Key Laboratory of Luminescent Materials and Devices and Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Wushan Road 381, Tianhe District, Guangzhou, 510640, Guangdong Province, P. R. China.
  • Chen Z; State Key Laboratory of Luminescent Materials and Devices and Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Wushan Road 381, Tianhe District, Guangzhou, 510640, Guangdong Province, P. R. China.
  • Gan Y; State Key Laboratory of Luminescent Materials and Devices and Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Wushan Road 381, Tianhe District, Guangzhou, 510640, Guangdong Province, P. R. China.
  • Su SJ; State Key Laboratory of Luminescent Materials and Devices and Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Wushan Road 381, Tianhe District, Guangzhou, 510640, Guangdong Province, P. R. China.
Angew Chem Int Ed Engl ; 61(35): e202209343, 2022 Aug 26.
Article em En | MEDLINE | ID: mdl-35816355
ABSTRACT
Highly efficient organic thermally activated delayed fluorescence (TADF) and room-temperature phosphorescence (RTP) emitters for organic light-emitting diodes (OLEDs) generally consist of a twisted donor-acceptor skeleton with aromatic amine donors. Herein, through introducing sulfur atoms into isomeric pentaphene and pentacene frameworks, we demonstrate a set of polycyclic luminophores exhibiting efficient TADF and RTP characters. The incorporation of sulfur atoms confirms a folded molecular plane, while intensifies singlet-triplet spin-orbit coupling. Further, the isomeric effect has a significant effect on the electronic structure of excited state, giving rise to the investigated compounds tunable luminescence mechanisms of TADF and RTP. With efficient triplet harvesting ability, maximum external quantum efficiencies up to 25.1 % and 8.7 % are achieved for the corresponding TADF and RTP OLEDs, verifying the great potential of sulfur-bridged frameworks for highly efficient devices.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2022 Tipo de documento: Article
Texto completo
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XML
PubMed Links
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2022 Tipo de documento: Article