Room-Temperature-Stable Magnesium Electride via Ni(II) Reduction.
J Am Chem Soc
; 144(29): 13109-13117, 2022 Jul 27.
Article
em En
| MEDLINE
| ID: mdl-35830190
ABSTRACT
Herein, we report the synthesis of highly reduced bipyridyl magnesium complexes and the first example of a stable organic magnesium electride supported by quantum mechanical computations and X-ray diffraction. These complexes serve as unconventional homogeneous reductants due to their high solubility, modular redox potentials, and formation of insoluble, non-coordinating byproducts. The applicability of these reductants is showcased by accessing low-valent (bipy)2Ni(0) species that are challenging to access otherwise.
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MEDLINE
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En
Ano de publicação:
2022
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Article