Chemical characterization of PM10 and PM2.5 combusted firecracker particles during Diwali of Lucknow City, India: air-quality deterioration and health implications.

ABSTRACT

Urban air pollution is a growing menace leading to human discomfort, increased hospitalizations, morbidity, and mortality. This study deals with deteriorated air quality due to firecracker bursting during Diwali in Lucknow. Inhalable particulates and gaseous pollutants were monitored during Diwali 2020 using air samplers. Elements, ions, and surface morphology of particles were analyzed using ICP-MS, ion chromatograph, and SEM-EDX, respectively. PM10, PM2.5, SO2, and NO2 were 558, 352, 44, and 86 µg/m3 during Diwali night and 233, 101, 17, and 40 µg/m3 on pre-Diwali night while 241, 122, 24, and 43 µg/m3 on Diwali day. Concentrations surged for PM10 139% and 132%, PM2.5 249% and 189%, SO2 159% and 83%, and NO2 115% and 100% on Diwali night compared to pre-Diwali night and corresponding Diwali day, respectively. Al, K, Ba, and B showed dominance in PM10 whereas Zn, Al, Ba, and K in PM2.5 on Diwali night. The order of metal abundance in PM2.5 was Cd < Co < Ag < As < Cr < Ni < Cu < Bi < Pb < Mn < Sr < Fe < B < Zn < Al < Ba < K. Cations NH4+, K+, Mg2+, Ca2+, and anions F-, Cl-, NO3-, Br-, NO2-, SO4-2, PO43- showed a 2-8 fold increase on Diwali night relative to pre-Diwali night. Average metal concentrations varied by 2.2, 1.6, and 0.09 times on Diwali than pre-Diwali in residential, commercial, and industrial areas, respectively. PM10 concentration increased by 458% and 1140% while PM2.5, 487%, and 2247% than respective NAAQS and WHO standards. Tiny firecracker particles vary in toxicity as compared to vehicular emissions and have enhanced bioavailability leading to severe threat in terms of LRI, COPD, and atherosclerosis for city dwellers. It is imperative to recognize the present status of ambient air quality and implement regulatory strategies for emission reduction.