Ambient synthesis of metal-covalent organic frameworks with Fe-iminopyridine linkages.
Chem Commun (Camb)
; 58(63): 8830-8833, 2022 Aug 04.
Article
em En
| MEDLINE
| ID: mdl-35848845
ABSTRACT
Highly crystalline Fe-COFs were constructed from the building blocks carrying pyridyl-aldehyde and triamine moieties in the presence of Fe(OTf)2 and acetic acid under ambient conditions via a subcomponent assembly strategy. The spectral results prove the coordination of atomically distributed Fe(II) ions with the nitrogen species of covalently formed iminopyridine linkages.
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MEDLINE
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En
Ano de publicação:
2022
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Article