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Ambient synthesis of metal-covalent organic frameworks with Fe-iminopyridine linkages.
Feng, Tiantian; Sun, Bing; Hao, Qing; Li, Jing; Xu, Ying; Shang, Hong; Wang, Dong.
Afiliação
  • Feng T; School of Science, China University of Geosciences (Beijing), Beijing 100083, P. R. China. sunbing@cugb.edu.cn.
  • Sun B; Key Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences and Beijing National Laboratory for Molecular Sciences, Beijing 100190, P. R. China. wangd@iccas.ac.cn.
  • Hao Q; School of Science, China University of Geosciences (Beijing), Beijing 100083, P. R. China. sunbing@cugb.edu.cn.
  • Li J; Key Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences and Beijing National Laboratory for Molecular Sciences, Beijing 100190, P. R. China. wangd@iccas.ac.cn.
  • Xu Y; Key Laboratory of Bio-inspired Smart Interfacial Science and Technology of Ministry of Education, School of Chemistry, Beihang University, Beijing 100191, P. R. China.
  • Shang H; Key Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences and Beijing National Laboratory for Molecular Sciences, Beijing 100190, P. R. China. wangd@iccas.ac.cn.
  • Wang D; School of Science, China University of Geosciences (Beijing), Beijing 100083, P. R. China. sunbing@cugb.edu.cn.
Chem Commun (Camb) ; 58(63): 8830-8833, 2022 Aug 04.
Article em En | MEDLINE | ID: mdl-35848845
ABSTRACT
Highly crystalline Fe-COFs were constructed from the building blocks carrying pyridyl-aldehyde and triamine moieties in the presence of Fe(OTf)2 and acetic acid under ambient conditions via a subcomponent assembly strategy. The spectral results prove the coordination of atomically distributed Fe(II) ions with the nitrogen species of covalently formed iminopyridine linkages.

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2022 Tipo de documento: Article

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2022 Tipo de documento: Article