Isolation and Reactivity of Tetrylene-Tetrylone-Iron Complexes Supported by Bis(N-Heterocyclic Imine) Ligands.
Angew Chem Int Ed Engl
; 61(39): e202208930, 2022 Sep 26.
Article
em En
| MEDLINE
| ID: mdl-35925668
ABSTRACT
The germanium iron carbonyl complex 3 was prepared by the reaction of dimeric chloro(imino)germylene [IPrNGeCl]2 (IPrN=bis(2,6-diisopropylphenyl)imidazolin-2-iminato) with one equivalent of Collman's reagent (Na2 Fe(CO)4 ) at room temperature. Similarly, the reaction of chloro(imino)stannylene [IPrNSnCl]2 with Na2 Fe(CO)4 (1â
equiv) resulted in the Fe(CO)4 -bridged bis(stannylene) complex 4. We observed reversible formation of bis(tetrylene) and tetrylene-tetrylone character in complexes 3 vs. 5 and 4 vs. 6, which was supported by DFT calculations. Moreover, the Li/Sn/Fe trimetallic complex 12 has been isolated from the reaction of [IPrNSnCl]2 with cyclopentadienyl iron dicarbonyl anion. The computational analysis further rationalizes the reduction pathway from these chlorotetrylenes to the corresponding complexes.
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MEDLINE
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Ano de publicação:
2022
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Article